Rhodium-phosphite Catalysed Hydroformylation of Camphene and Other Terpenes

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Rhodium-phosphite Catalysed Hydroformylation of Camphene and Other Terpenes

February 9, 2021 Chemical Science 0

With homogeneous Rh, Co, and Pt metal complexes, the hydroformylation of camphene and other terpenes has been studied. The catalyst system of Rh(CO)2(acac)/P(OPh)3 was found to be very active with almost complete selectivity for aldehyde products. The position of ligands, solvents, Rh:P ratio and conditions of reaction to camphene hydroformylation activity and selectivity have been evaluated. Camphene hydroformylation kinetics were investigated in the presence of the catalyst [Rh(CO)2(acac)]/P(OPh)3 in a temperature range of 363-383K.

Author (s) Details

Dr. Nitin S. Pagar
Homogeneous Catalysis Division, CSIR-National Chemical Laboratory, Dr. Homi Bhabha Road, Pune 411008, India and Post Graduate Department of Chemistry, Sir Parshurambhau College, (Affiliated to Savitribai Phule Pune University), Pune-411030, India.

Dr. Raj M. Deshpande
Homogeneous Catalysis Division, CSIR-National Chemical Laboratory, Dr. Homi Bhabha Road, Pune 411008, India.

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