Synthesis of Acylals from Aromatic Aldehydes and Their Deprotections Catalyzed by Synthetic Phosphates: Practical and Ecological Approach

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Synthesis of Acylals from Aromatic Aldehydes and Their Deprotections Catalyzed by Synthetic Phosphates: Practical and Ecological Approach

February 9, 2021 Chemical Science 0

Effective and clean preparation of aromatic aldehyde acylals in the presence of synthetic phosphates (flourapatite and hydroxyapatite doped with ZnCl2 and ZnBr2) and acetic anhydride was easily achieved under solvent-free conditions at room temperature at high yields (86% – 97%). The deprotection of the resulting acylum was also accomplished by using the same microwave irradiation catalysts. Excellent yields (82 percent – 96 percent) and a quick reaction time are consistently advantaged by this strategy (3 – 4 min).

Author (s) Details

Fathallaah Bazi
Laboratoire de Chimie Analytique et physicochimie des Matériaux, Université Hassan II, Faculté des Sciences Ben M’Sik, Casablanca, Morocco.

Bahija Mounir
Laboratoire de Chimie Analytique et physicochimie des Matériaux, Université Hassan II, Faculté des Sciences Ben M’Sik, Casablanca, Morocco.

Mohammed Hamza
Laboratoire de Chimie Analytique et physicochimie des Matériaux, Université Hassan II, Faculté des Sciences Ben M’Sik, Casablanca, Morocco.

Said Sebti
Laboratoire de Chimie Physique Catalyse et Environnement, Université Hassan II, Faculté des Sciences Ben M’Sik, Casablanca, Morocco.

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