A Recent Study on the Synthesis and DFT Collaborated Experimental Characterization of Some Pyrazolone Functionalized Dioxovanadium(V) Schiff Base Complexes
The goal of this paper is to synthesise and characterise dioxovanadium(V) complexes of semicarbazone ONO-donor ligands, LH [where LH = N-(4′-benzoylidene-3′-methyl-1′-phenyl-2′-pyrazolin-5′-one)-semicarbazone (bmphp-semH), N-(4′-butylidene-3′-methyl By oxidising bis(acetylacetonato) oxovanadium(IV) complexes of the above ligands with ambient oxygen (bubbling air) for 2-3 days, they were generated from ethanol-methanol mixed solvent (1/10) solutions of bis(acetylacetonato) oxovanadium(IV) complexes of the…
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