Solution Behavior and Optical Properties of Platinum Complexes Featuring “Pt(pq)(C≡CtBu)” Units Connected by N-donor Ligands

It presents the synthesis, spectroscopic (including X-ray for 2a and 4a) and optical properties of a sequence of binuclear complexes [{Pt(pq)(C ⁇ CtBu)}2{μ-(N-N)}] (1a-5a), ditopic dinitrogen connector ligands (N-N) and trinuclear ligands [{Pt(pq)(C ⁇ CtBu)}3(μ-L)] (6a) with a central core of 1,3,5-tris(pyridine-4ylethynyl)benzene. Particular attention in this chapter is devoted to the peculiar behaviour of complex…
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November 4, 2020 0